Re: [CH] CH Inexpensive PH meter

T. Matthew Evans (matt.evans@ce.gatech.edu)
Mon, 13 Aug 2001 10:34:18 -0400 (EDT)

Quoting "Scates, Dannie" <dannies@aiinet.com>:

> Also I would like to learn how to relate PH to Percentage of acetic
> acid, as
> in vinegar. 
> Thank You
> Dannie
> 

At first glance, it would seem relatively simple to convert pH into percent 
acetic acid, because acetic is a monoprotic acid.  Thus, the pH equation is 
easily solvable using a spreadsheet (i.e., it is a third-order polynomial).  
However, if one reconsiders, this problem becomes deceptively nontrivial....  
The reason is that there will be a significant number of additional reactions 
occurring during the cooking process.  So, there will be lots of other ions 
floating around in your vegetable-vinegar soup.  You can get a close 
approximation using analytical methods, but to really ground-truth your acetic 
acid content, you would need a gas chromatograph (and then, assume no secondary 
reactions with the acetate ion during canning).

Reply off-list if you are interested in the analytical approximation.

Matt


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